At least for your first question I may give you some hints: A good overview for I²S compatibility is provided by this spreadsheet on page 2. There are some small but fundamental differences in the pinout configuration of different manufacturers.
And just search the web for reports of compatibility to different brands, and of course ask the specific manufacturer.
Regarding the second question maybe some owners of PWT, DMP or PST might chime in. I banned CD-transports years ago…
But anyway, if you already decided to get the PS Audio transport, just see (and hear) if it is your taste!
When I was using the PWD Mk II DAC there was a distinct difference between using the I2S and the AES/EBU and other inputs from a transport or other source.
With the DSD DAC though Ted has noted that he worked hard to make all inputs less distinct from one another with equally low jitter etc. (Of course for DSD and SACD the I2S must be used). I have my PST connected with both I2S via HDMI and AES/EBU and I have to say. . . the differences are very subtle if there at all, and seem to be related to the cabling itself more than the connection format. So if only using a transport for Redbook. . . either connection method works well. As for differing transports I had the PWT, the DMP and the PST. There’s a significant bump from PWT to DMP, a less large a bump from DMP to PST in my experience.